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There are a couple which have defeated me over the years but I refuse to cut necks so I have had to resort to a lot of different options. The best one ever is heat - I have wrapped a neck in white cotton (normally a bit of old pillow case) and poured very very very hot (be careful) water over it. Repeat it often enough or continue it long enough and most plastic will eventually soften. Although I have also learned patience is key!
I'm curious as to how it looks? You keep saying it's fused.
Have you tried using a hair dryer to heat the seal? I've used a hair dryer to remove Funko Pop heads.
Oh dear, sorry about your pony dilemma! It is *possible* that at some stage someone has glued the pony's head back on with superglue. Superglue is terrible stuff, and helpful parents love it. With regards to your worry about the hairdryer burning the hair, it hasn't on any of mine where I have used my hairdryer to heat up the neck seal and loosen it. I prefer to use the hairdryer on stubborn neck seals personally and have never had a problem.Don't leave the rust inside the pony though as it will continue to corrode and the pony will eventually become stained. Good luck!
I have to agree with the hair dryer... (I've put many heads back on with this method as well.) If push comes to shove you could try dental floss or string dipped in acetone and work it into the neck seam. You just have to be careful to not get the acetone anywhere else on the pony...